Title : Triggering Electron Transfer in Co(I) Dimers: Computational Evidences for a Reversible Disproportionation Mechanism.

Pub. Date : 2021 Apr 19

PMID : 33529486






2 Functional Relationships(s)
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1 A detailed analysis of the electronic structure of Cobalt dimers of the general formula Co2Cl2Ln (L = NH3 and PH3) demonstrates that electron transfer is triggered by asymetric coordination of amine and phosphine to stabilize a mixed-valence Co(II)-Co(0) dimer. Amines mitochondrially encoded cytochrome c oxidase II Homo sapiens
2 This is consistent with the HSAB statement that both amine and phosphine ligands are required to stabilize the reaction products, respectively Co(II) and Co(0) centers. Amines mitochondrially encoded cytochrome c oxidase II Homo sapiens