Title : Iron Catalyzed Double Bond Isomerization: Evidence for an FeI /FeIII Catalytic Cycle.

Pub. Date : 2021 Apr 1

PMID : 33492679






1 Functional Relationships(s)
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1 The data obtained support a pre-catalyst activation step that gives access to an eta 2 -coordinated alkene Fe(I) complex, followed by oxidative addition of the alkene to give an Fe(III) intermediate, which then undergoes reductive elimination to allow release of the isomerization product. Alkenes DNA polymerase iota Homo sapiens