Title : Ligand Field Inversion as a Mechanism to Gate Bioorganometallic Reactivity: Investigating a Biochemical Model of Acetyl CoA Synthase Using Spectroscopy and Computation.

Pub. Date : 2021 Jan 20

PMID : 33415980






3 Functional Relationships(s)
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Protein Name
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1 The biological global carbon cycle is largely regulated through microbial nickel enzymes, including carbon monoxide dehydrogenase (CODH), acetyl coenzyme A synthase (ACS), and methyl coenzyme M reductase (MCR). Nickel acyl-CoA synthetase short chain family member 2 Homo sapiens
2 The biological global carbon cycle is largely regulated through microbial nickel enzymes, including carbon monoxide dehydrogenase (CODH), acetyl coenzyme A synthase (ACS), and methyl coenzyme M reductase (MCR). Nickel acyl-CoA synthetase short chain family member 2 Homo sapiens
3 We have established a mutant of nickel-substituted azurin as a scaffold upon which to develop protein-based models of enzymatic intermediates, including the organometallic states of ACS. Nickel acyl-CoA synthetase short chain family member 2 Homo sapiens