Title : Radical Rearrangement of Aryl/Alkylidene Malononitriles via Aza Michael Addition/Decynoformylation/Addition Sequence: An Access to α-Aminonitriles and α-Aminoamides.

Pub. Date : 2020 Dec 4

PMID : 33146011






1 Functional Relationships(s)
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1 An efficient, safe, and environmentally friendly tertiary butyl hydrogen peroxide (TBHP)-mediated rearrangement of aryl/alkylidene malononitrile with anilines has been developed with in situ generation of HCN as the cyanide source for the synthesis of substituted alpha-aminonitriles and alpha-aminoamide. tert-Butylhydroperoxide metastasis associated lung adenocarcinoma transcript 1 Homo sapiens