Title : High-Pressure-Promoted and Facially Selective Diels-Alder Reactions of Enzymatically Derived cis-1,2-Dihydrocatechols and Their Acetonide Derivatives: Enantiodivergent Routes to Homochiral and Polyfunctionalized Bicyclo[2.2.2]octenes.

Pub. Date : 2020 Oct 16

PMID : 32914974






1 Functional Relationships(s)
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1 cis-1,2-dihydrocatechols 5 (X= Me and Cl), which are available in homochiral form through the whole-cell biotransformation of toluene and chlorobenzene, respectively, undergo Diels-Alder cycloaddition reactions with certain electron-deficient dienophiles at 19 kbar (1.9 GPa). Toluene suppressor of cytokine signaling 1 Homo sapiens