Title : C-H Amination Mediated by Cobalt Organoazide Adducts and the Corresponding Cobalt Nitrenoid Intermediates.

Pub. Date : 2020 Jun 24

PMID : 32456423






1 Functional Relationships(s)
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1 Unlike (ArL)CoBr(N3(C6H4-p-tBu)), a series of alkyl azide-bound CoII analogues expel N2 only above 60 C, affording paramagnetic intermediates that convert to the corresponding Co-imine complexes via alpha-H-atom abstraction. Nitrogen mitochondrially encoded cytochrome c oxidase II Homo sapiens