Title : In Situ NMR Search for Spin-Crossover in Heteroleptic Cobalt(II) Complexes.

Pub. Date : 2020 Jun 1

PMID : 32383584






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1 In Situ NMR Search for Spin-Crossover in Heteroleptic Cobalt(II) Complexes. Cobalt(2+) spindlin 1 Homo sapiens
2 Screening the spin state of a cobalt(II) ion in a series of thus obtained homoleptic and heteroleptic compounds of terpyridines (terpy) and 2,6-bis(pyrazol-3-yl)pyridines (3-bpp) by using this NMR-based approach, which only relies on the temperature behavior of chemical shifts, revealed the first cobalt(II) complexes with a 3-bpp ligand to undergo a thermally induced spin-crossover. Cobalt(2+) spindlin 1 Homo sapiens
3 Screening the spin state of a cobalt(II) ion in a series of thus obtained homoleptic and heteroleptic compounds of terpyridines (terpy) and 2,6-bis(pyrazol-3-yl)pyridines (3-bpp) by using this NMR-based approach, which only relies on the temperature behavior of chemical shifts, revealed the first cobalt(II) complexes with a 3-bpp ligand to undergo a thermally induced spin-crossover. Cobalt(2+) spindlin 1 Homo sapiens
4 Screening the spin state of a cobalt(II) ion in a series of thus obtained homoleptic and heteroleptic compounds of terpyridines (terpy) and 2,6-bis(pyrazol-3-yl)pyridines (3-bpp) by using this NMR-based approach, which only relies on the temperature behavior of chemical shifts, revealed the first cobalt(II) complexes with a 3-bpp ligand to undergo a thermally induced spin-crossover. Cobalt(2+) spindlin 1 Homo sapiens