Title : Chemoselective oxidative addition of vinyl sulfones mediated by palladium complexes bearing picolyl-N-heterocyclic carbene ligands.

Pub. Date : 2020 May 7

PMID : 32293627






1 Functional Relationships(s)
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Protein Name
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1 (E)-1,2-Ditosylethene produces the expected and stable eta2-olefin palladium complexes, whereas the coordination of the Z derivative alternatively promotes the isomerization of the olefin itself or an oxidative addition process depending on the steric bulkiness of carbene substituents and/or the adopted synthetic procedure. Alkenes DNA polymerase iota Homo sapiens