Title : Control over the Redox Cooperative Mechanism of Radical Carbene Transfer Reactions for the Efficient Active-Metal-Template Synthesis of [2]Rotaxanes.

Pub. Date : 2020 Jun 23

PMID : 32022364






1 Functional Relationships(s)
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Protein Name
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1 Coordination of Co(II) ions into the porphyrin subunit followed by addition of appropriate monodentate nitrogen-based additives to function as axial ligands enable the radical carbene transfer reactions to styrene derivatives to occur exclusively through the cavity of the macrocycle to afford cyclopropane-linked rotaxanes in excellent 95% yield. Nitrogen mitochondrially encoded cytochrome c oxidase II Homo sapiens