Title : Switchable Polymerization Triggered by Fast and Quantitative Insertion of Carbon Monoxide into Cobalt-Oxygen Bonds.

Pub. Date : 2020 Apr 6

PMID : 32017360






3 Functional Relationships(s)
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1 The key phenomenon is a rapid and quantitative insertion of CO into the Co-O bond, allowing for in situ transformation of the ROCOP active species (Salen)Co III -OR into the OMRP photoinitiator (Salen)Co III -CO 2 R. The proposed mechanism, which involves CO coordination to (Salen)Co III -OR and subsequent intramolecular rearrangement via migratory insertion has been rationalized by DFT calculations. 12-(4'-azido-2'-nitrophenoxy)dodecanoyl-coenzyme A mitochondrially encoded cytochrome c oxidase III Homo sapiens
2 The key phenomenon is a rapid and quantitative insertion of CO into the Co-O bond, allowing for in situ transformation of the ROCOP active species (Salen)Co III -OR into the OMRP photoinitiator (Salen)Co III -CO 2 R. The proposed mechanism, which involves CO coordination to (Salen)Co III -OR and subsequent intramolecular rearrangement via migratory insertion has been rationalized by DFT calculations. 12-(4'-azido-2'-nitrophenoxy)dodecanoyl-coenzyme A mitochondrially encoded cytochrome c oxidase III Homo sapiens
3 The key phenomenon is a rapid and quantitative insertion of CO into the Co-O bond, allowing for in situ transformation of the ROCOP active species (Salen)Co III -OR into the OMRP photoinitiator (Salen)Co III -CO 2 R. The proposed mechanism, which involves CO coordination to (Salen)Co III -OR and subsequent intramolecular rearrangement via migratory insertion has been rationalized by DFT calculations. 12-(4'-azido-2'-nitrophenoxy)dodecanoyl-coenzyme A mitochondrially encoded cytochrome c oxidase III Homo sapiens