Title : Exopolyhedral Ligand Orientation Controls Diastereoisomer in Mixed-Metal Bis(carboranes).

Pub. Date : 2020 Jan 24

PMID : 31991685






1 Functional Relationships(s)
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1 It is suggested that the preferred exopolyhedral ligand orientation in the rhodacarboranes in the non-observed diastereoisomers would lead to unacceptable steric crowding between the PPh3 ligand and either the p-cymene (compound 1) or Cp (compound 2) ligand of the ruthenacarborane or cobaltacarborane, respectively. 4-cymene caveolin 1 Homo sapiens