Title : Stereochemistry of coordination polyhedra vs. single ion magnetism in penta- and hexacoordinated Co(ii) complexes with tridentate rigid ligands.

Pub. Date : 2020 Jan 28

PMID : 31904039






2 Functional Relationships(s)
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1 A tridentate ligand L (2,6-bis(1-(3,5-di-tert-butylbenzyl)-1H-benzimidazol-2-yl)pyridine) was synthesized and used for the preparation of three pentacoordinated Co(ii) complexes of formula [Co(L)X2] (where X = NCS- for 1, X = Cl- for 2 and X = Br- for 3) and one ionic compound 4 ([Co(L)2]Br2 2CH3OH H2O) containing a hexacoordinated Co(ii) centre. 12-(4'-azido-2'-nitrophenoxy)dodecanoyl-coenzyme A mitochondrially encoded cytochrome c oxidase II Homo sapiens
2 A tridentate ligand L (2,6-bis(1-(3,5-di-tert-butylbenzyl)-1H-benzimidazol-2-yl)pyridine) was synthesized and used for the preparation of three pentacoordinated Co(ii) complexes of formula [Co(L)X2] (where X = NCS- for 1, X = Cl- for 2 and X = Br- for 3) and one ionic compound 4 ([Co(L)2]Br2 2CH3OH H2O) containing a hexacoordinated Co(ii) centre. 12-(4'-azido-2'-nitrophenoxy)dodecanoyl-coenzyme A mitochondrially encoded cytochrome c oxidase II Homo sapiens