Title : Titanocene(III)-Mediated 5-exo-trig Radical Cyclization: En Route to Spirooxindole-Based Tetrahydrofuran and Bicyclic Lactone.

Pub. Date : 2019 Dec 20

PMID : 31793298






1 Functional Relationships(s)
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1 Herein we depict an isatin-derived and 3,3"-di-substituted oxindole-appended epoxy-acrylate undergoing Cp2Ti(III)Cl-mediated reductive oxirane-ring opening with concomitant intramolecular 5-exo-trig radical cyclization leading to tetrahydrofuran based oxa-spirooxindole systems. Isatin ceruloplasmin Homo sapiens