Title : Efficient Generation and Synthetic Applications of Alkyl-Substituted Siloxycarbenes: Suppression of Norrish-Type Fragmentations of Alkanoylsilanes by Triplet Energy Transfer.

Pub. Date : 2020 Jan 27

PMID : 31702842






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1 In this study, generation of siloxycarbenes from alkanoylsilanes by visible-light-induced energy transfer was examined by using an Ir complex, [Ir{dF(CF 3 )ppy} 2 (dtbpy)]PF 6 , and was successfully applied to the C-C coupling reactions with boronic esters or aldehydes. siloxycarbenes sperm associated antigen 17 Homo sapiens