Title : Phosphine-Catalyzed [4+2] Cycloadditions of Allenic Ketones: Enantioselective Synthesis of Functionalized Tetrahydropyridines.

Pub. Date : 2019 Oct 1

PMID : 31508886






1 Functional Relationships(s)
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1 Amino-acid-derived phosphine catalyzed [4+2] cycloaddition leading to chiral tetrahydropyridines, making use of alpha-substituted allenic ketones as "C4 synthons" and N-sulfonyl cyclic ketimines, has been developed. Pyrrolidines complement C4A (Rodgers blood group) Homo sapiens