Title : Probing through-space and through-bond magnetic exchange couplings in a new benzotriazinyl radical and its metal complexes.

Pub. Date : 2019 Oct 7

PMID : 31508635






8 Functional Relationships(s)
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Protein Name
Organism
1 The reaction of Rad2 with the 3d transition metal complexes M(hfac)2 xH2O (hfac- = hexafluoroacetylacetonate) led to mononuclear metal complexes of general formula M(hfac)2(Rad2) [M = Zn(ii) (1); Ni(ii) (2) and Co(ii) (3)] whose structures have been determined by single crystal X-ray diffraction. Metals mitochondrially encoded cytochrome c oxidase II Homo sapiens
2 The reaction of Rad2 with the 3d transition metal complexes M(hfac)2 xH2O (hfac- = hexafluoroacetylacetonate) led to mononuclear metal complexes of general formula M(hfac)2(Rad2) [M = Zn(ii) (1); Ni(ii) (2) and Co(ii) (3)] whose structures have been determined by single crystal X-ray diffraction. Metals mitochondrially encoded cytochrome c oxidase II Homo sapiens
3 The reaction of Rad2 with the 3d transition metal complexes M(hfac)2 xH2O (hfac- = hexafluoroacetylacetonate) led to mononuclear metal complexes of general formula M(hfac)2(Rad2) [M = Zn(ii) (1); Ni(ii) (2) and Co(ii) (3)] whose structures have been determined by single crystal X-ray diffraction. Metals mitochondrially encoded cytochrome c oxidase II Homo sapiens
4 The reaction of Rad2 with the 3d transition metal complexes M(hfac)2 xH2O (hfac- = hexafluoroacetylacetonate) led to mononuclear metal complexes of general formula M(hfac)2(Rad2) [M = Zn(ii) (1); Ni(ii) (2) and Co(ii) (3)] whose structures have been determined by single crystal X-ray diffraction. Metals mitochondrially encoded cytochrome c oxidase II Homo sapiens
5 The reaction of Rad2 with the 3d transition metal complexes M(hfac)2 xH2O (hfac- = hexafluoroacetylacetonate) led to mononuclear metal complexes of general formula M(hfac)2(Rad2) [M = Zn(ii) (1); Ni(ii) (2) and Co(ii) (3)] whose structures have been determined by single crystal X-ray diffraction. Metals mitochondrially encoded cytochrome c oxidase II Homo sapiens
6 The reaction of Rad2 with the 3d transition metal complexes M(hfac)2 xH2O (hfac- = hexafluoroacetylacetonate) led to mononuclear metal complexes of general formula M(hfac)2(Rad2) [M = Zn(ii) (1); Ni(ii) (2) and Co(ii) (3)] whose structures have been determined by single crystal X-ray diffraction. Metals mitochondrially encoded cytochrome c oxidase II Homo sapiens
7 In the case of the Zn(ii) complex (1) through-space intermolecular radicalradical antiferromagnetic exchange interactions via pi*pi* contacts are observed, whereas strong intramolecular through-bond metal-radical ferromagnetic interactions [J = +59.3(9) cm-1] are observed for the Ni(ii) complex (2). Metals mitochondrially encoded cytochrome c oxidase II Homo sapiens
8 For the Co(ii) complex (3), computational and magnetic studies reveal substantial zero field splitting and ferromagnetic metal-radical interactions. Metals mitochondrially encoded cytochrome c oxidase II Homo sapiens