Title : Rhodium(iii)-catalyzed diverse [4 + 1] annulation of arenes with 1,3-enynes via sp3/sp2 C-H activation and 1,4-rhodium migration.

Pub. Date : 2019 Apr 14

PMID : 31015939






1 Functional Relationships(s)
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1 Herein we describe rhodium(iii)-catalyzed sp2 and sp3 C-H activation-oxidative annulations between aromatic substrates and 1,3-enynes, where alkenyl-to-allyl 1,4-rhodium(iii) migration enabled the generation of electrophilic rhodium(iii) pi-allyls via remote C-H functionalization. Rhodium Sp2 transcription factor Homo sapiens