Title : Dioxygen insertion into the gold(i)-hydride bond: spin orbit coupling effects in the spotlight for oxidative addition.

Pub. Date : 2016 Dec 1

PMID : 30996862






2 Functional Relationships(s)
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Protein Name
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1 Dioxygen insertion into the gold(i)-hydride bond: spin orbit coupling effects in the spotlight for oxidative addition. Oxygen spindlin 1 Homo sapiens
2 O2 insertion into a Au(i)-H bond occurs through an oxidative addition/recombination mechanism, showing peculiar differences with respect to Pd(ii)-H, for which O2 insertion takes place through a hydrogen abstraction mechanism in the triplet potential energy surface with a pure spin transition state. Oxygen spindlin 1 Homo sapiens