Title : Cis-1,4-Polymerization of Isoprene by 1,3-Bis(oxazolinymethylidene)isoindoline-Ligated Rare-Earth Metal Dialkyl Complexes.

Pub. Date : 2017 Oct 20

PMID : 30965837






2 Functional Relationships(s)
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1 In the presence of a cocatalyst such as borate and AlR3, these complexes 1-3 exhibit high activities of up to 6.8 x 104 (g of polymer)/(molLn h) and high cis-1,4 selectivities of up to 97% in the polymerization of isoprene in toluene, yielding the cis-1,4-polyisoprenes with heavy molecular weights (Mn of up to 710,000 g/mol) and bimodal molecular weight distributions (Mw/Mn = 2.0-4.5). Toluene suppressor of cytokine signaling 1 Homo sapiens
2 In the presence of a cocatalyst such as borate and AlR3, these complexes 1-3 exhibit high activities of up to 6.8 x 104 (g of polymer)/(molLn h) and high cis-1,4 selectivities of up to 97% in the polymerization of isoprene in toluene, yielding the cis-1,4-polyisoprenes with heavy molecular weights (Mn of up to 710,000 g/mol) and bimodal molecular weight distributions (Mw/Mn = 2.0-4.5). Toluene suppressor of cytokine signaling 1 Homo sapiens