Title : Cooperative Co0 /CoII Sites Stabilized by a Perovskite Matrix Enable Selective C-O and C-C bond Hydrogenolysis of Oxygenated Arenes.

Pub. Date : 2019 May 21

PMID : 30848866






2 Functional Relationships(s)
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1 CoII sites associated with oxygen vacancies were favored at low temperatures and performed selective C-O hydrogenolysis, in which Sr-substitution facilitated oxygen vacancy formation, leading to approximately 10 times higher reactivity compared to undoped LaCoO3 . Oxygen mitochondrially encoded cytochrome c oxidase II Homo sapiens
2 CoII sites associated with oxygen vacancies were favored at low temperatures and performed selective C-O hydrogenolysis, in which Sr-substitution facilitated oxygen vacancy formation, leading to approximately 10 times higher reactivity compared to undoped LaCoO3 . Oxygen mitochondrially encoded cytochrome c oxidase II Homo sapiens