Title : Spin Interconversion of Heme-Peroxo-Copper Complexes Facilitated by Intramolecular Hydrogen-Bonding Interactions.

Pub. Date : 2019 Mar 27

PMID : 30836005






1 Functional Relationships(s)
Download
Sentence
Compound Name
Protein Name
Organism
1 Synthetic peroxo-bridged high-spin (HS) heme-(mu-eta2:eta1-O22-)-Cu(L) complexes incorporating (as part of the copper ligand) intramolecular hydrogen-bond (H-bond) capabilities and/or steric effects are herein demonstrated to affect the complex"s electronic and geometric structure, notably impacting the spin state. Hydrogen DNA polymerase iota Homo sapiens