Title : Reactivity toward Unsaturated Small Molecules of Thiolate-Bridged Diiron Hydride Complexes.

Pub. Date : 2018 Dec 17

PMID : 30485081






1 Functional Relationships(s)
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1 In the presence of 1 equiv of tBuNC, the homolytic cleavage of the FeIII-H bond in the diiron terminal hydride complex [Cp*Fe( t-H)(mu-eta2:eta4-bdt)FeCp*][BF4] (1[BF4]) smoothly took place to release 1/2 H2, followed by binding of a tBuNC group to the unsaturated FeII center. Creatinine DNA polymerase iota Homo sapiens