Title : Modulation of σ-Alkane Interactions in [Rh(L2)(alkane)]+ Solid-State Molecular Organometallic (SMOM) Systems by Variation of the Chelating Phosphine and Alkane: Access to η2,η2-σ-Alkane Rh(I), η1-σ-Alkane Rh(III) Complexes, and Alkane Encapsulation.

Pub. Date : 2018 Nov 7

PMID : 30351014






1 Functional Relationships(s)
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1 CH2Cl2 adducts formed by displacement of the eta1-alkanes in solution ( n = 5; L = NBA, COA), [ RhH(Cy2P(CH2)2( CH)(CH2)2PCy2)(kappa1-ClCH2Cl)][BArF4], are characterized crystallographically. Methylene Chloride secreted phosphoprotein 1 Homo sapiens