Title : Tuning Expanded Pores in Metal-Organic Frameworks for Selective Capture and Catalytic Conversion of Carbon Dioxide.

Pub. Date : 2018 Nov 9

PMID : 30129103






1 Functional Relationships(s)
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1 Gas sorption results for these highly mesoporous materials show that alternately arranged fused benzene rings on one side of the ligand could serve as extra anchoring sites for CO2 molecules with pi-pi interactions, conspicuously enhancing CO2 uptake and CO2 /CH4 and CO2 /N2 selectivity; while more steric hindrance effect towards open CoII sites were imposed by ligands flanked with fused benzene rings on both sides, compromising such extra-sites enhancement. Methane mitochondrially encoded cytochrome c oxidase II Homo sapiens