Title : Electrochemistry and Spectroelectrochemistry of Cobalt Porphyrins with π-Extending and/or Highly Electron-Withdrawing Pyrrole Substituents. In Situ Electrogeneration of σ-Bonded Complexes.

Pub. Date : 2018 Feb 5

PMID : 29363959






1 Functional Relationships(s)
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1 Chemically or electrochemically generated Co(I) porphyrins are known to be highly reactive in solutions containing alkyl or aryl halides, and this property was utilized to in situ generate a new series of methyl carbon-bonded cobalt(III) porphyrins with the same pi-extending or highly electron-withdrawing substituents as the initial Co(II) derivatives. halides mitochondrially encoded cytochrome c oxidase I Homo sapiens