Pub. Date : 2015 Jul 1
PMID : 29218203
2 Functional Relationships(s)Download |
Sentence | Compound Name | Protein Name | Organism |
| 1 | Moreover, the calculations reveal that formation of the hydrosilane adducts proceeds via barrierless electrophilic activation of the hydrosilane by sterically controlled eta1 (end-on) or eta2 (side-on) coordination of the Si-H bond to the Lewis acidic metal center, followed by heterolytic cleavage of the Si-H bond through a concerted four-membered transition state. | Silicon | secreted phosphoprotein 1 | Homo sapiens |
| 2 | Moreover, the calculations reveal that formation of the hydrosilane adducts proceeds via barrierless electrophilic activation of the hydrosilane by sterically controlled eta1 (end-on) or eta2 (side-on) coordination of the Si-H bond to the Lewis acidic metal center, followed by heterolytic cleavage of the Si-H bond through a concerted four-membered transition state. | Silicon | secreted phosphoprotein 1 | Homo sapiens |