Title : Carbonylative Coupling of Alkyl Zinc Reagents with Benzyl Bromides Catalyzed by a Nickel/NN2  Pincer Ligand Complex.

Pub. Date : 2018 Jan 15

PMID : 29193522






1 Functional Relationships(s)
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1 An efficient catalytic protocol for the three-component assembly of benzyl bromides, carbon monoxide, and alkyl zinc reagents to give benzyl alkyl ketones is described, and represents the first nickel-catalyzed carbonylative coupling of two sp3 -carbon fragments. Nickel Sp3 transcription factor Homo sapiens