Title : Redox-Active Bis(phenolate) N-Heterocyclic Carbene [OCO] Pincer Ligands Support Cobalt Electron Transfer Series Spanning Four Oxidation States.

Pub. Date : 2017 Oct 16

PMID : 28968088






1 Functional Relationships(s)
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1 Combined experimental and computational data suggest that the charge-neutral four-coordinate complexes are best formulated as Co(II) centers bound to closed-shell [OCO]2- dianions, of the general formula [(OCO)CoIIL] (where L is a solvent-derived MeCN or THF). acetonitrile mitochondrially encoded cytochrome c oxidase II Homo sapiens