Title : 4-Diazoisochroman-3-imines: A Class of Metal Carbene Precursors for the Synthesis of Isochromene Derivatives.

Pub. Date : 2017 Oct 20

PMID : 28952315






1 Functional Relationships(s)
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1 Under the catalysis from a Rh(II) complex, this class of alpha-diazo imidates reacted with alkenes and conjugated dienes through a formal [2 + 1] (i.e., cyclopropanation) or [4 + 3] cycloaddition to furnish spiro[cyclopropane-1,4"-isochroman]-3"-imines and tetrahydroisochromeno[3,4-b] azepines, respectively. Alkenes Rh blood group D antigen Homo sapiens