Title : Mechanistic insight into selective catalytic combustion of HCN over Cu-BEA: influence of different active center structures.

Pub. Date : 2017 Sep 13

PMID : 28831469






1 Functional Relationships(s)
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1 However, an oxidation mechanism (HCN oxidized into NH radical and CO2 through intermediate of HNCO) combining with a hydrolysis mechanism (NH radical hydrolyses into NH3) occurred over single [Cu]+ and [Cu-O-Cu]2+, wherein the NH2 hydrolysis to NH3 step was regarded as the rate determining step with an energy barrier of 72.3 and 74.3 kcal mol-1, respectively. N2,N6-bis(4-(2-aminoethoxy)quinolin-2-yl)-4-((4-fluorobenzyl)oxy)pyridine-2,6-dicarboxamide metastasis associated lung adenocarcinoma transcript 1 Homo sapiens