Title : Switchable Stereoselectivity in Bromoaminocyclization of Olefins: Using Brønsted Acids of Anionic Chiral Cobalt(III) Complexes.

Pub. Date : 2017 Sep 18

PMID : 28745445






1 Functional Relationships(s)
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1 The diastereomeric chiral CoIII -templated Bronsted acids, with the same chiral ligands, enabled a switch in the enantioselective bromoaminocyclization of olefins to afford the two enantiomers of 2-substituted pyrrolidines with high enantioselectivities (up to 99:1 e.r. Alkenes mitochondrially encoded cytochrome c oxidase III Homo sapiens