Title : Novel CoIII complexes containing fluorescent coumarin-N-acylhydrazone hybrid ligands: Synthesis, crystal structures, solution studies and DFT calculations.

Pub. Date : 2017 Dec 5

PMID : 28683368






1 Functional Relationships(s)
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1 Cyclic voltammetry studies showed that structural modifications made in the L2- ligands caused a slight influence on the electronic density of the metal center, and the E1/2 values for the CoIII/CoII redox couple increased following the electronic effect of the R-substituent, in the order: 2 (R=OCH3)<1 (R=H)<3 (R=Cl). Metals mitochondrially encoded cytochrome c oxidase II Homo sapiens