Title : Products of Criegee intermediate reactions with NO2: experimental measurements and tropospheric implications.

Pub. Date : 2017 Aug 24

PMID : 28604897






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1 The reactions of Criegee intermediates with NO2 have been proposed as a potentially significant source of the important nighttime oxidant NO3, particularly in urban environments where concentrations of ozone, alkenes and NOx are high. Nitrogen Dioxide NBL1, DAN family BMP antagonist Homo sapiens
2 NO3 is not observed; however, temporally resolved and [NO2]-dependent signal is observed at the mass of the Criegee-NO2 adduct for both formaldehyde- and acetaldehyde-oxide systems, and the structure of this adduct is explored through ab initio calculations. Nitrogen Dioxide NBL1, DAN family BMP antagonist Homo sapiens
3 NO3 is not observed; however, temporally resolved and [NO2]-dependent signal is observed at the mass of the Criegee-NO2 adduct for both formaldehyde- and acetaldehyde-oxide systems, and the structure of this adduct is explored through ab initio calculations. Nitrogen Dioxide NBL1, DAN family BMP antagonist Homo sapiens