Title : Diverse Reactivity of an Electrophilic Phosphasilene towards Anionic Nucleophiles: Substitution or Metal-Amino Exchange.

Pub. Date : 2016 Aug 26

PMID : 27509901






2 Functional Relationships(s)
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1 The reaction of MesLi (Mes=2,4,6-trimethylphenyl) with the electrophilic phosphasilene R2 (NMe2 )Si-RSi=PNMe2 (2, R=Tip=2,4,6-triisopropylphenyl) cleanly affords R2 (NMe2 )Si-RSi=PMes and thus provides the first example of a substitution reaction at an unperturbed Si=P bond. 2-(N-morpholino)ethanesulfonic acid NME/NM23 nucleoside diphosphate kinase 2 Homo sapiens
2 The reaction of MesLi (Mes=2,4,6-trimethylphenyl) with the electrophilic phosphasilene R2 (NMe2 )Si-RSi=PNMe2 (2, R=Tip=2,4,6-triisopropylphenyl) cleanly affords R2 (NMe2 )Si-RSi=PMes and thus provides the first example of a substitution reaction at an unperturbed Si=P bond. 2-(N-morpholino)ethanesulfonic acid NME/NM23 nucleoside diphosphate kinase 2 Homo sapiens