Title : Mechanistic Insights into the Cu(I)- and Cu(II)-Catalyzed Cyclization of o-Alkynylbenzaldehydes: The Solvent DMF and Oxidation State of Copper Affect the Reaction Mechanism.

Pub. Date : 2015 Jul 2

PMID : 26034833






1 Functional Relationships(s)
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1 (c) The 6-endo product P1 is formed exclusively using a catalytic system consisting of CuCl and DMF, whereas a mixture of 6-endo product P1 and 5-exo product P2 in a ratio of ~1:1 is produced using CuCl2 and DMF as a catalytic system. cupric chloride crystallin gamma F, pseudogene Homo sapiens