Title : Positive Effect of Water in Asymmetric Direct Aldol Reactions with Primary Amine Organocatalyst: Experimental and Computational Studies.

Pub. Date : 2015 Oct

PMID : 25873417






1 Functional Relationships(s)
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1 As suggested by the calculated transition-state structures for water-promoted imine-enamine isomerization, anti-selective aldol reaction and hemiaminal formation, the rate of this aldol reaction was found experimentally to be even more accelerated by the addition of cis-2-butene-1,4-diol as additive. cyclopentyl enamine suppressor of cytokine signaling 2 Homo sapiens