Title : HCN elimination from vinyl cyanide: product energy partitioning, the role of hydrogen-deuterium exchange reactions and a new pathway.

Pub. Date : 2015 Mar 14

PMID : 25679300






2 Functional Relationships(s)
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1 HCN elimination from vinyl cyanide: product energy partitioning, the role of hydrogen-deuterium exchange reactions and a new pathway. Hydrogen metastasis associated lung adenocarcinoma transcript 1 Homo sapiens
2 The KMC simulations carried out using singly deuterated VCN (CH2=CD-CN) at 148 kcal mol(-1) show the importance of hydrogen-deuterium exchange reactions: both DCN and HCN will be produced in any of the 1,1 and 1,2 elimination pathways. Hydrogen metastasis associated lung adenocarcinoma transcript 1 Homo sapiens