Title : Dinuclear rare-earth metal alkyl complexes supported by indolyl ligands in μ-η(2) :η(1) :η(1) hapticities and their high catalytic activity for isoprene 1,4-cis-polymerization.

Pub. Date : 2015 Feb 2

PMID : 25490879






1 Functional Relationships(s)
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1 In the process, the indole unit of L1 is deprotonated by the metal alkyl species and the imino C=N group is transferred to the amido group by alkyl CH2 SiMe3 insertion, affording a new dianionic ligand that bridges two metal alkyl units in mu-eta(2) :eta(1) :eta(1) bonding modes, forming the dinuclear rare-earth metal alkyl complexes. Carbon DNA polymerase iota Homo sapiens