Title : Effect of axial ligand, spin state, and hydrogen bonding on the inner-sphere reorganization energies of functional models of cytochrome P450.

Pub. Date : 2014 Oct 6

PMID : 25238648






3 Functional Relationships(s)
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1 Effect of axial ligand, spin state, and hydrogen bonding on the inner-sphere reorganization energies of functional models of cytochrome P450. Hydrogen cytochrome P450 family 4 subfamily F member 3 Homo sapiens
2 The results suggest that while the hydrogen bonding to the thiolate in the 5C HS thiolate bound active site of cytochrome P450 (cyp450) shifts the potential up, resulting in a negative DeltaG, it also increases lambda resulting in an overall low barrier for the electron transfer process. Hydrogen cytochrome P450 family 4 subfamily F member 3 Homo sapiens
3 The results suggest that while the hydrogen bonding to the thiolate in the 5C HS thiolate bound active site of cytochrome P450 (cyp450) shifts the potential up, resulting in a negative DeltaG, it also increases lambda resulting in an overall low barrier for the electron transfer process. Hydrogen cytochrome P450 family 4 subfamily F member 3 Homo sapiens