Title : The photophysics of fac-[Re(CO)3(NN)(bpa)](+) complexes: a theoretical/experimental study.

Pub. Date : 2014 Aug

PMID : 24967638






1 Functional Relationships(s)
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1 The emission lifetime and quantum yield decrease significantly in fac-[Re(CO)3(dpq)(bpa)](+) (phi = 0.05; tau = 375 ns) due to the presence of a close lying dark charge transfer state located at the pyrazine ring of dpq, as indicated by TD-DFT data. Pyrazines FA complementation group C Homo sapiens