Title : Synthesis and electrochemistry of β-pyrrole nitro-substituted cobalt(II) porphyrins. The effect of the NO₂ group on redox potentials, the electron transfer mechanism and catalytic reduction of molecular oxygen in acidic media.

Pub. Date : 2014 Jul 28

PMID : 24882526






1 Functional Relationships(s)
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1 Each neutral Co(II) porphyrin was also examined as to its catalytic activity for electroreduction of molecular oxygen when coated on an edge-plane pyrolytic graphite electrode in 1.0 M HClO4. Oxygen mitochondrially encoded cytochrome c oxidase II Homo sapiens