Title : Construction of homoallylic alcohols from terminal alkynes and aldehydes with installation of syn-stereochemistry.

Pub. Date : 2014 Apr 30

PMID : 24735355






2 Functional Relationships(s)
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1 Construction of homoallylic alcohols from terminal alkynes and aldehydes with installation of syn-stereochemistry. Aldehydes synemin Homo sapiens
2 A cationic rhodium(I) catalyst turns 2-silyl-1-alkenylboronate, readily prepared from a terminal alkyne, into the corresponding allylboronate species, which immediately undergoes nucleophilic addition to an aldehyde to give a syn-homoallylic alcohol stereoselectively. Aldehydes synemin Homo sapiens