Title : Cobalt triarylcorroles containing one, two or three nitro groups. Effect of NO₂ substitution on electrochemical properties and catalytic activity for reduction of molecular oxygen in acid media.

Pub. Date : 2014 Jul

PMID : 24507930






2 Functional Relationships(s)
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1 Each compound can undergo two metal-centered one-electron reductions leading to formation of Co(II) and Co(I) derivatives in CH2Cl2 or pyridine containing 0.1 M tetra-n-butylammonium perchlorate (TBAP). Methylene Chloride mitochondrially encoded cytochrome c oxidase II Homo sapiens
2 Thin-layer UV-visible spectroelectrochemical measurements in CH2Cl2, 0.1 M TBAP demonstrate the occurrence of an equilibrium between a Co(III) pi-anion radical and a Co(II) derivative with an uncharged macrocycle after the first controlled potential reduction of the nitro-substituted corroles. Methylene Chloride mitochondrially encoded cytochrome c oxidase II Homo sapiens