Title : Closer to photosystem II: a Co4O4 cubane catalyst with flexible ligand architecture.

Pub. Date : 2013 Dec 18

PMID : 24279370






2 Functional Relationships(s)
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1 We introduce the novel Co4O4 complex [Co(II)4(hmp)4(mu-OAc)2(mu2-OAc)2(H2O)2] (1) (hmp = 2-(hydroxymethyl)pyridine) as the first Co(II)-based cubane water oxidation catalyst. Water mitochondrially encoded cytochrome c oxidase II Homo sapiens
2 The Co(II) core combines robustness and stability with flexibility through a new type of water-oxidation mechanism via mobile ligands. Water mitochondrially encoded cytochrome c oxidase II Homo sapiens