Title : Structural and electronic properties of old and new A2[M(pin(F))2] complexes.

Pub. Date : 2013 Dec 16

PMID : 24261319






2 Functional Relationships(s)
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1 Together, these data demonstrate that perfluorination of the pinacolate ligand makes possible highly unusual and coordinatively unsaturated high-spin metal centers with ready thermodynamic access to rare oxidation states such as Ni(III) and Cu(III). Metals mitochondrially encoded cytochrome c oxidase III Homo sapiens
2 Together, these data demonstrate that perfluorination of the pinacolate ligand makes possible highly unusual and coordinatively unsaturated high-spin metal centers with ready thermodynamic access to rare oxidation states such as Ni(III) and Cu(III). Metals mitochondrially encoded cytochrome c oxidase III Homo sapiens