Title : Ni-catalyzed reductive homocoupling of unactivated alkyl bromides at room temperature and its synthetic application.

Pub. Date : 2013 Nov 1

PMID : 24087851






2 Functional Relationships(s)
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1 Moreover, the dimerization of tertiary bromide 6 efficiently establishes sterically hindered vicinal quaternary carbons (C3a and C3a"), which is a key linkage of intriguing bispyrrolo[2,3-b]indoline alkaloids, thereby enabling us to complete the total syntheses of racemic chimonanthine (9) and folicanthine (10). Carbon complement C3 Homo sapiens
2 Moreover, the dimerization of tertiary bromide 6 efficiently establishes sterically hindered vicinal quaternary carbons (C3a and C3a"), which is a key linkage of intriguing bispyrrolo[2,3-b]indoline alkaloids, thereby enabling us to complete the total syntheses of racemic chimonanthine (9) and folicanthine (10). Carbon complement C3 Homo sapiens