Title : One-pot synthesis of α-amino acids from CO2 using a bismetal reagent with Si-B bond.

Pub. Date : 2012 Dec 21

PMID : 23205912






1 Functional Relationships(s)
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1 In the presence of 1.1 equiv of PhMe(2)Si-Bpin, 5 equiv of CsF, and 20 mol % of TsOH H(2)O, precursors of N-Boc-imines can be converted into the corresponding alpha-aryl or alpha-alkenyl glycine derivatives under gaseous CO(2) in moderate-to-high yields with a single operation. co(2) colony stimulating factor 2 Homo sapiens