Title : Structural, spectroscopic and redox properties of a mononuclear Co(II) thiolate complex--the reactivity toward S-alkylation: an experimental and theoretical study.

Pub. Date : 2012 Oct 28

PMID : 22960784






1 Functional Relationships(s)
Download
Sentence
Compound Name
Protein Name
Organism
1 The cyclic voltammogram (CV) displays two one-electron metal based processes: a quasi-reversible Co(III)/Co(II) oxidation wave at E(1/2) = -0.5 V vs. Fc(+)/Fc and a quasi-reversible Co(II)/Co(I) reduction wave at E(1/2) = -1.7 V. 1 reacts with CH(3)I, generating the mono S-methylated complex, [CoL(Me)I] (1(Me)). Metals mitochondrially encoded cytochrome c oxidase III Homo sapiens