Title : trans-[Ru(II)(dpp)Cl2]: a convenient reagent for the preparation of heteroleptic Ru(dpp) complexes, where dpp is 2,9-di(pyrid-2'-yl)-1,10-phenanthroline.

Pub. Date : 2012 Mar 5

PMID : 22324974






1 Functional Relationships(s)
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1 When the precursor trans-[Ru(II)(dpp)Cl(2)] reacts with a bidentate (2,2"-bipyridine), tridentate (2,2";6,2""-terpyridine), or tetradentate (itself) ligand, a peripheral pyridine on dpp is displaced such that dpp binds as a tridentate. 2,2'-Dipyridyl dentin sialophosphoprotein Homo sapiens