Title : Synthesis and characterization of cobalt(II) complexes with tripodal polypyridine ligand bearing pivalamide groups. Selective formation of six- and seven-coordinate cobalt(II) complexes.

Pub. Date : 2012 Apr 14

PMID : 22301678






2 Functional Relationships(s)
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1 The former Co(II) complexes revealed a six-coordinate octahedron with one amine nitrogen, three pyridyl nitrogens, and two counter anions, and one coordinated anion, Cl(-), Br(-) and N(3)(-), forming intramolecular hydrogen bonds with two pivalamide N-H groups. Amines mitochondrially encoded cytochrome c oxidase II Homo sapiens
2 On the other hand, the latter Co(II) complexes showed a seven-coordinate face-capped octahedron with one amine nitrogen, three pyridyl nitrogens, two pivalamide carbonyl oxygens and MeCN or MeOH. Amines mitochondrially encoded cytochrome c oxidase II Homo sapiens